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A-level Chemistry: 3.3.12 Polymers

Chemical Engineering31 CardsCreated about 1 month ago

This set of flashcards covers condensation polymers, focusing on polyamides—their monomer components, the type of bond formed (amide link), examples such as Nylon 6,6 and Kevlar, and their common uses. It highlights the chemical basis and practical applications of these polymers.

Name 3 examples of condensation polymers

  • polyamides

  • polyesters

  • polypeptides

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Key Terms

Term
Definition

Name 3 examples of condensation polymers

  • polyamides

  • polyesters

  • polypeptides

What are polyamides made out of?

Dicarboxylic acids + diamines

Polyamides

State the name of the bond that forms between the carboxyl
groups and amino groups

Amide link

Name 2 examples of polyamides

  1. Nylon 6,6

  2. Kevlar

State what nylon 6,6 is made from

1,6-diaminohexane + hexanedioic acid

Name some uses of nylon 6,6

Used to make clothing, carpet, rope, airbags and parachutes

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TermDefinition

Name 3 examples of condensation polymers

  • polyamides

  • polyesters

  • polypeptides

What are polyamides made out of?

Dicarboxylic acids + diamines

Polyamides

State the name of the bond that forms between the carboxyl
groups and amino groups

Amide link

Name 2 examples of polyamides

  1. Nylon 6,6

  2. Kevlar

State what nylon 6,6 is made from

1,6-diaminohexane + hexanedioic acid

Name some uses of nylon 6,6

Used to make clothing, carpet, rope, airbags and parachutes

Draw an equation showing how nylon 6,6 is formed

State what kevlar is made from

1,4-diaminobenzene and benzene-1,4-dicarboxylic acid

Name some uses of kevlar

Used in bulletproof vests, boat construction, car tyres and lightweight spots equipment

Draw an equation showing how kevlar is formed

What are polyesters made out of?

Dicarboxylic acids + diols

Polyesters

State the name of the bond that forms between the carboxyl
groups and hydroxyl groups

Ester link

Name an example of polyester

Terylene (PET)

State what terylene (PET) is made from

Benzene-1,4-dicarboxylic acid and ethane-1,2diol

Name some uses of terylene (PET)

Used in plastic bottles, clothing, sheets and sails


Condensation polymers are ______ than addition polymers


stronger & more rigid

Why are condensation polymers stronger & more rigid than addition polymers?

  • ∵ made up of chains contains polar bonds e.g. C-N and C-O

  • ∴ have Van der Waals forces, permanent dipole-dipole forces and hydrogen bonds between polymer chains

Why are polyalkenes (addition polymers) non-biodegradable and won’t react when being used?

Have non-polar C-C bonds = unreactive and chemically inert

Why are condensation polymers biodegradable?

  • polar bonds (e.g. C=O) in chains = open to attack by nucleophiles

  • ∴ can be broken down by hydrolysis

  • ∴ are biodegradable but process is very slow

Name 3 ways of disposing waste plastics

  • Burying in landfill

  • Burning as fuel

  • Recycling

When are plastics placed in landfills?

When plastic is:

  • Difficult to separate from other waste

  • Not in sufficient quantities to make separation financially worthwhile

  • Too difficult technically to recycle

Name an advantage of using landfills to dispose plastics

Landfill is cheap and easy method of waste disposal

Name 3 disadvantages of using landfills to dispose plastics

  • Requires areas of land

  • As waste decomposes, can release methane = greenhouse effect

  • Leaks from landfill contaminate water supplies

What is an advantage of burning plastics (excluding its cost and ease)?

Heat can be used to generate electricity

Why when burning waste plastics, does the process need to be carefully controlled?

To reduce release of toxic gases

e.g. polymers that contain chlorine (PVC) produce HCl when burned = has to be removed

Burning Waste Plastics

How is the release of toxic gases reduced?

Waste gases from combustion as passed through scrubbers which neutralise gases like HCl by allowing them to react with a base

What is a disadvantage of burning waste plastics?

Waste gases e.g. CO2 will still contributed to greenhouse effect

Name 2 ways to recycle plastics

  • Some plastics can be melted and remoulded

  • Some plastics can be cracked into monomers & these can be used to make more plastics or other chemicals

Name 4 advantages of recycling waste plastics

  • Reduces amount of waste going into landfill

  • Saves raw materials, oil = non-renewable

  • Cost of recycling plastics is lower than making plastics from scratch

  • Produces less CO2 emissions than burning plastic

Name 4 disadvantages of recycling waste plastics

  • It is technically difficult to recycle plastics

  • Collecting, sorting and processing plastic is more expensive than burning/landfill

  • Often can't remake the plastic you started with, have to make something else

  • Plastic can be easily contaminated during the recycling process

1,4-butanedioic acid