Chemistry - Oxidation and Reduction Flashcards Part 1
Oxidation is defined as the gain of oxygen by a substance. It often occurs alongside reduction in redox reactions. Oxidation and reduction can be understood in three ways: Addition or removal of oxygen, Transfer of electrons, Change in oxidation number
list the three ways of looking at oxidation and reduction
addition or removal of oxygen
transfer of electrons
oxidation number
Key Terms
list the three ways of looking at oxidation and reduction
addition or removal of oxygen
transfer of electrons
oxidation number
what are oxidtion reactions defined as in terms of addition or removal of oxygen
Gaining oxygen
what are reduction reactions defined as in terms of addition or removal of oxygen
loss of oxygen
what is reduction In terms of oxygen
the removal of oxygen or the addition of hydrogen
Displacement reaction of metal oxides in terms of addition or removal of oxygen
a more reactive metal will displace a less reactive metal from a compound
describe the thermite reaction
produce:white hot molten iron in remote locations.
alminium + Iron(III)oxide -> Iron + aluminium oxide
Alminium removes oxygen from iron o...
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| Term | Definition |
|---|---|
list the three ways of looking at oxidation and reduction | addition or removal of oxygen |
what are oxidtion reactions defined as in terms of addition or removal of oxygen | Gaining oxygen |
what are reduction reactions defined as in terms of addition or removal of oxygen | loss of oxygen |
what is reduction In terms of oxygen | the removal of oxygen or the addition of hydrogen |
Displacement reaction of metal oxides in terms of addition or removal of oxygen | a more reactive metal will displace a less reactive metal from a compound |
describe the thermite reaction | produce:white hot molten iron in remote locations. |
What is a displacement reaction of solutions in terms of addition or removal of oxygen | A more reactive metal will displace a less reactive metal from a solution of one of its salts |
Name an example of a displacement reaction in terms of addition or removal of oxygen | Magnesium + copper(II) sulfate -> copper + magnesium sulfate. |
What is oxidation of an element In terms of electron transfer | oxidation of an element takes place when it loses electrons |
what is reduction of an element In terms of electron transfer | reduction of an elemnet takes place when it gains electrons |
Why do oxidation and reduction reactions occour together In terms of electron transfer | When one reactant loses electrons the other has to gain electrons |
Describe the Zinc and copper sulfate reaction | oxidation and reduction takes place.zinc becomes covered with a reddish deposit which is the copper metal.The blue colour of the solution fades-which implies the copper metals are being used up.This is a redox reaction and a displacement reaction. |
What is a redox reaction | a reaction where oxidation and reduction occour simultaneously.( one cannout occour without the other) |
an oxidation agent | substance that brings about oxidation in other substances |
an reducing agent | substance that brings about reduction in other substances |
What is oxidation number |
|
what is electronegativity | A the force of attraction that an atoms has for a shared pair of electrons |
What is oxidation in terms of ON | A increase in oxidation number |
what is reduction in terms of ON |
|
oxidation number rules that have an expection | A oxygen oxidation number is always(-2). expect in peroxides(bonded with hydrogen) expect with a more electronegative element. Hydrogen ON number is always +1 expect in metal hydrites where its -1 halogens ON is always -1 expect bonded to a more electronegative element |
What is transition metal | an element that forms at least one ion with a partially filled d sublevel |
Physical properties of transition elements | A good conductors of heat and electricity hammered or bend into shape easily high melting points hard + tough high densities |
chemical properties of transition elements | less reactive than alkali metals form coloured ions of different charges some are very unreactive many used as catlysts |
applications of oxidising agents | A hyprogen peroxide (H2O2) used to bleach hair (coloured pigment + H2O2-> colourless hair pogment + H2O chlorine in swimming pools.Cl2 is oxidising agent household bleaches. Sodium hypochloride (NaClO) |
describe the reactions of the halogens | Reaction with hallides-compared to other halogens | the halogens are very reactive elements and cannot exist in a uncombined form. They act as oxdising agents (take an electron from another element) clorine is the strongest non dangerous element. Its capable of releasing bromine and iodine form a solutions of its salts F>Cl>Br>I>At |
What is the colour of Chlorine in water | Pale green |
What is the colour of Bromine in water | Yellow/ orange |
What is the colour of Iodine in water | Brown/red |
What is the colour of Chloride ions in water | Colourless |
What is the colour of Bromide ions in water | Colourless |
What is the colour of Iodide ions in water | Colourless |
describe the conversion of Fe2+ to Fe3+ | all three halogen solutions are able to oxidise iron(II) ions into iron (III) ions. in two seperate test tubes. add iron(II) sulfate and iron(III) chloride add sodium hydroxide (NAOH) Iron (II)sulfate + NaOH = Fe(OH)2 -> green percipate Iron (III) chloride + NaOH = Fe(OH)3 -> brown percipate Add chlorine water to Fe(OH)2 (when Cl2 is added to the Fe2+ mixture is oxdises the Fe2+ to Fe3+ (green - brown) |
Describe the expeirment for oxidising sulfite ions | So3 2- --> So4 2- add sodium sulfite to test tube add chlorine (no change) add BaCl2 (white ppt forms) add HCl (white ppt stays) this proves the presence of sulfate ions |
Describe the displacement of metals | Magnesium and Zinc are respectivily reacted with a solution of copper (II) sulfate Colour of CuSO4 at beginning Blue Colour at end colourless colour of ppt formed Brown other observations Gas evolved In both casrs the metal (magnesium/zinc) displaces the copper from its salts Blue to colourless No CU2+ ions present |