graph), calculate k from the data. rate= k [S^2O^5 * 2 -|* x |*|*|*|*| | (for solution 2 | | | 3 | | --- | --- | --- | --- | | | | | | | Chemical Reactions 1: | | | | | A Clock Reaction | | | | | A. Preliminary Experiments | | | | | 1. | | | | | 2. | | | | | 3. | | | | | 4. | | | | | B. Kinetics Experiment | | | | | Solution 1. Initial [S^2O^5 * 2 -|* x 0.05 M; initial [1 1 - 0.005 M. Time experiment started | | | | | | | | | | Aliquot no. | Time (s) between | | Total moles of | | | appearances of color | Cumulative times (s) | S^2O^5 * consumed | | 1 | 18.5 | 18.5 | 2.0×10 - 4 | | 2 | 19.0 | 27.0 | 4.0×10 - 4 | | 3 | 20.0 | 29.0 | 6.0×10 - 4 | | 4 | 21.5 | 31.5 | 8.0×10 - 4 | | 5 | 22.0 | 32.0 | 10×10 - 4 | | 6 | 23.5 | 33.5 | 12×10 - 4 | | 7 | 24.5 | 35.0 | 14×10 - 4 | | | | | | | Solution 2. Initial [S^2O^5 * 2 - 0.10 M; initial [1 1 - 0.010 M. Time experiment started | | | | | | | | | | Aliquot no. | Time (s) between | | Total moles of | | | appearances of color | Cumulative times (s) | S^2O^5 * consumed | | 1 | 4.0 | 4.0 | 2.0×10 - 4 | | 2 | 4.5 | 5.0 | 4.0×10 - 4 | | 3 | 5.5 | 6.0 | 6.0×10 - 4 | | 4 | 6.5 | 7.0 | 8.0×10 - 4 | | 5 | 7.0 | 8.0 | 10×10 - 4 | | 6 | 8.0 | 9.0 | 10×10 - 4 | | 7 | 9.0 | 10.0 | 12×10 - 4 | | | | | | | Solution 3. Initial [S^2O^5 * 2 - 0.05 M; initial [1 1 - 0.010 M. Time experiment started | | | | | | | | | | Aliquot no. | Time (s) between | | Total moles of | | | appearances of color | Cumulative times (s) | S^2O^5 * consumed | | 1 | 13.5 | 13.5 | 4.0×10 - 4 | | 2 | 13.0 | 14.0 | 6.0×10 - 4 | | 3 | 13.5 | 14.5 | 8.0×10 - 4 | | 4 | 14.5 | 15.0 | 10×10 - 4 | | 5 | 15.5 | 16.0 | 12×10 - 4 | | 6 | 16.0 | 17.0 | 14×10 - 4 | | 7 | 17.0 | 18.0 | 14×10 - 4 | | | | | | | Solution 4. Initial [S^2O^5 * 2 - 0.10 M; initial [1 1 - 0.025 M. Time experiment started | | | | | | | | | | Aliquot no. | Time (s) between | | Total moles of | | | appearances of color | Cumulative times (s) | S^2O^5 * consumed | | 1 | 19.5 | 19.5 | 2.0×10 - 4 | | 2 | 19.5 | 20.0 | 4.0×10 - 4 | | 3 | 20.5 | 21.5 | 6.0×10 - 4 | | 4 | 21.5 | 22.0 | 8.0×10 - 4 | | 5 | 22.0 | 23.0 | 10×10 - 4 | | 6 | 23.5 | 24.5 | 12×10 - 4 | | 7 | 25.0 | 25.5 | 14×10 - 4 | | | | | |
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Answer

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Step 1
I'll solve this kinetics problem by calculating the rate constant k for each solution using the integrated rate law method.

I'll focus on Solution 2 as an example.

Step 2
: Identify the Reaction Order

- Rate law appears to be: $$rate = k[S_{2}O_{5}^{2-}]^{x}[I^{-}]^{y}
- The problem involves determining the rate law and rate constant

Final Answer

- k = slope / ([A]_{0}^{n- 1}), where n is reaction order