Q
QuestionChemistry

"Which formula/name pair is incorrect? A. FeSO₄ - iron(II) sulfate B. Fe₂(SO₃)₃ - iron(III) sulfite C. FeS - iron(II) sulfide D. FeSO₃ - iron(II) sulfite E. Fe₂(SO₄)₃ - iron(III) sulfide"
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Answer

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Step 1
: Identify the correct formula-name pairs.

Iron can have oxidation states of + 2 or + 3. When it has an oxidation state of + 2, it is called iron(II), and when it has an oxidation state of + 3, it is called iron(III). Sulfate has a charge of - 2, sulfite has a charge of - 2, and sulfide has a charge of - 2. To balance the charges, we need to ensure that the sum of the oxidation states of iron equals the total charge on the sulfate, sulfite, or sulfide ion.

Step 2
: Analyze each option.

A. FeSO₄ - iron(II) sulfate: Correct. The sulfate ion has a charge of - 2, so iron must have an oxidation state of + 2 to balance the charge, which is iron(II). B. Fe₂(SO₃)₃ - iron(III) sulfite: Correct. The sulfite ion has a charge of - 2, so three sulfite ions will have a total charge of - 6. Two iron atoms with an oxidation state of + 3 will have a total charge of + 6, balancing the charge. C. FeS - iron(II) sulfide: Correct. The sulfide ion has a charge of - 2, so iron must have an oxidation state of + 2 to balance the charge, which is iron(II).

Final Answer

The incorrect formula-name pair is FeSO₃ - iron(II) sulfite.