Q
QuestionChemistry

"Which is more highly regioselective, the reaction of an alkene with BH^3 or with 9 -BBN? A. The reaction of an alkene with BH^3 B. The reaction of an alkene with 9 -BBN"
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Answer

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Step 1
I'll solve this problem step by step, focusing on the regioselectivity of hydroboration reactions:

Step 2
: Understanding Hydroboration Reactions

Hydroboration is an important organic reaction where borane (BH3) or 9 -borabicyclo[3.3.1]nonane (9 -BBN) adds to an alkene. The key consideration is regioselectivity - how the boron adds to an unsymmetrical alkene.

Final Answer

The reaction of an alkene with 9 -BBN is more highly regioselective. Key Insight: The bulky structure of 9 -BBN provides superior control over the boron addition compared to the smaller, more symmetric BH^3 molecule.