Test Bank For Organic Chemistry, 7th Edition

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BIAF 7e Test Bank 1
CHAPTER 1—COVALENT BONDING AND SHAPES OF MOLECULES
MULTIPLE CHOICE
1. How many electrons can the shell with a principal quantum number of 1 hold?
a. 1
b. 2
c. 4
d. 8
ANS: B
2. How many electrons can the shell with a principal quantum number of 2 hold?
a. 1
b. 2
c. 4
d. 8
ANS: D
3. What is the ground-state electronic configuration of a nitrogen atom (nitrogen: atomic number 7)?
a. 1s22s12p4
b. 1s22s22p3
c. 1s12s12p5
d. 1s22s22p2
ANS: B
4. What is the ground-state electronic configuration of a fluorine atom (fluorine: atomic number 9)?
a. 1s12s12p7
b. 1s22s22p5
c. 1s22s22p6
d. 1s02s22p7
ANS: B
5. What is the ground-state electronic configuration of a fluoride anion (fluorine: atomic number 9)?
a. 1s22s22p2
b. 1s22s22p5
c. 1s22s22p6
d. 1s22s22p7
ANS: C
6. What is the ground-state electronic configuration of a sodium cation (sodium: atomic number 11)?
a. 1s22s22p63s1
b. 1s22s22p53s1
c. 1s22s22p6
d. 1s22s22p63s2
ANS: C

BIAF 7e Test Bank 2
7. Which of the following species has an atom that has an unfilled valence shell of electrons?
a. molecular hydrogen, H2
b. hydroxide anion, HO−
c. boron trifluoride, BF3
d. water, H2O
ANS: C
8. Which of the following species has an atom that has an unfilled valence shell of electrons?
a. molecular bromine, Br2
b. fluoride anion, F−
c. ammonia, NH3
d. aluminum trichloride, AlCl3
ANS: D
9. Which of the following species possesses a formal charge?
a. BH3
b. BH4
c. CCl4
d. H2S
ANS: B
10. Which of the following species possesses a formal charge?
a. CCl4
b. SiCl4
c. AlCl4
d. PCl3
ANS: C
11. Which of the following compounds is an aldehyde?
a. CH3CH2CH2COOH
b. CH3CH2CHO
c. CH3CH2CH2OH
d. CH3CH2COCH3
ANS: B
12. Which of the following compounds is an alcohol?
a. CH3CH2COOH
b. CH3CH2OCH3
c. CH3CH2CH2OH
d. CH3CH2CHO
ANS: C
13. Which of the following compounds is a carboxylic acid?
a. CH3CH2COOH
b. CH3CH2OCH3
c. CH3CH2CH2OH
d. CH3CH2CHO
ANS: A

BIAF 7e Test Bank 3
14. Which of the following compounds is a ketone?
a. CH3CH2COOH
b. CH3CH2CHO
c. CH3CH2CH2OH
d. CH3COCH3
ANS: D
15. Which of the following compounds is a ketone?
a. CH3CH2COOH
b. CH3CH2CHO
c. CH3CH2CH2OH
d. CH3COCH3
ANS: D
16. Which of the following compounds is a carboxylic ester?
a. CH3CH2COOH
b. CH3CH2OCH3
c. CH3CH2COOCH3
d. CH3CH2COCH3
ANS: C
17. Which of the following is a tertiary alcohol?
a. CH3CH2OCH3
b. (CH3)3COH
c. (CH3)2CHOH
d. CH3CH2CH2OH
ANS: B
18. Which of the following is a tertiary amine?
a. CH3CH2N(CH3)2
b. (CH3)3CNH2
c. CH3CH2NHCH3
d. CH3CH2NHCH(CH3)2
ANS: A
19. Which of the following is a primary amine?
a. CH3CH2NHCH3
b. CH3CH2NHCH(CH3)2
c. CH3CH2N(CH3)2
d. (CH3)3CNH2
ANS: D
20. Which of the following is trigonal planar?
a. boron trifluoride, BF3
b. methyl anion, CH3−
c. methane, CH4
d. ammonia, NH3
ANS: A

BIAF 7e Test Bank 4
21. Which of the following molecules is not linear?
a. H2O
b. CO2
c. HCCH
d. Cl2
ANS: A
22. What is the approximate value of the H−C−H bond angles in methane, CH4?
a. 90
b. 109
c. 120
d. 180
ANS: B
23. What is the approximate C−C−C bond angle in propene, CH3CH=CH2?
a. 90
b. 109
c. 120
d. 180
ANS: C
24. What is the approximate C−C−C bond angle in propyne, HCCCH3?
a. 90
b. 109
c. 120
d. 180
ANS: D
25. What is the approximate H−C−O bond angle in formaldehyde, H2C=O?
a. 90
b. 109
c. 120
d. 180
ANS: C
26. Which of the following elements has the highest electronegativity?
a. N
b. C
c. O
d. S
ANS: C
27. Which of the following elements has the highest electronegativity?
a. C
b. P
c. Si
d. Cl
ANS: D

BIAF 7e Test Bank 5
28. Which of the following bonds is the most polar?
a. F−F
b. H−F
c. C−H
d. C−Si
ANS: B
29. Which of the following bonds is the most polar?
a. O−H
b. C−H
c. C−C
d. H−H
ANS: A
30. Which of the following bonds is a polar covalent bond?
a. Na−F
b. C−H
c. C−O
d. Cl−Cl
ANS: C
31. Which of the following bonds is a polar covalent bond?
a. Na−Cl
b. C−Cl
c. C−H
d. Cl−Cl
ANS: B
32. Which of the following is an ionic bond?
a. Br−Br
b. C−Cl
c. C−S
d. Na−O
ANS: D
33. Which of the following is an ionic bond?
a. F−F
b. C−H
c. Li−O
d. C−N
ANS: C
34. Which of the following bonds has the smallest dipole moment?
a. C−N
b. C−O
c. C−F
d. O−H

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BIAF 7e Test Bank 6
ANS: A
35. Which of the following bonds has the smallest dipole moment?
a. Li−Cl
b. C−H
c. O−H
d. H−Cl
ANS: B
36. Which of the following molecules has a molecular dipole moment?
a. 1
b. 2
c. 3
d. 4
ANS: B
37. Which of the following molecules has a molecular dipole moment?
a. 1
b. 2
c. 3
d. 4
ANS: B
38. Which of the following molecules has a molecular dipole moment?
a. CO2
b. BF3
c. NH3
d. CH4
ANS: C
39. Which of the following molecules has a molecular dipole moment?
a. H2O
b. CO2
c. HCCH
d. Cl2
ANS: A

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BIAF 7e Test Bank 7
40. Which of the following best represents the shape of the 2s atomic orbital of carbon?
a. 1
b. 2
c. 3
d. 4
ANS: A
41. Which of the following best represents the shape of a 2p atomic orbital of carbon?
a. 1
b. 2
c. 3
d. 4
ANS: B
42. Which of the following best represents an sp2 hybridized atomic orbital of carbon which overlaps with
the 1s atomic orbital of hydrogen to form a C−H  bonding molecular orbital in ethene, H2C=CH2
a. 1
b. 2
c. 3
d. 4
ANS: C
43. Which of the following best represents an sp3 hybridized atomic orbital containing the lone pair of
electrons of ammonia, NH3?

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BIAF 7e Test Bank 8
a. 1
b. 2
c. 3
d. 4
ANS: C
44. Which atomic orbitals overlap to form the C=O bond of acetone, (CH3)2C=O?
a. C 2sp3 + O 2sp2
b. C 2sp2 + O 2p
c. C 2sp2 + O 2sp2
d. C 2sp3 + O 2sp
ANS: C
45. Which atomic orbitals overlap to form the C−O bond of dimethyl ether, (CH3)2O?
a. C 2sp3 + O 2sp2
b. C 2sp2 + O 2p
c. C 2sp2 + O 2sp2
d. C 2sp3 + O 2sp3
ANS: D
46. What is the approximate value of the length of the C=C bond in ethane, CH2=CH2?
a. 121 pm
b. 134 pm
c. 142 pm
d. 154 pm
ANS: B
47. What is the approximate value of the length of the CC bond in ethyne, HCCH?
a. 121 pm
b. 134 pm
c. 142 pm
d. 154 pm
ANS: A
48. Which of the following statements is not true regarding resonance structures?
a. All resonance structures must have the same number of electrons
b. Each atom in all of the resonance structures must have a complete shell of valence
electrons
c. All resonance structures must have the same arrangement of atoms
d. All resonance structures must be valid Lewis structures
ANS: B
49. Which of the following statements is not true regarding resonance structures?
a. Each resonance structure is in rapid equilibrium with all of the other structures
b. The resonance structures may have different energies
c. All resonance structures must have the same arrangement of atoms
d. All resonance structures must have the same number of electrons

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BIAF 7e Test Bank 9
ANS: A
50. Which of the following statements is not true about the carbonate anion, CO32−?
a. All of the oxygen atoms bear the same amount of charge
b. All of the carbon-oxygen bonds are the same length
c. The carbon atom bears the negative charge
d. It is basic
ANS: C
51. Which of the following statements is not true about the acetate anion, CH3CO2−?
a. The oxygen atoms bear the same amount of charge
b. The two carbon-oxygen bonds are the same length
c. The carbon atom bears the negative charge
d. It is basic
ANS: C
52. Rank the following in order of decreasing importance as a contributing resonance structure to the
molecular structure of acetone, CH3COCH3 (more important > less important)
a. 1 > 2 > 3
b. 1 > 3 > 2
c. 2 > 1 > 3
d. 3 > 1 > 2
ANS: B
53. Which of the following resonance structures is the least important contributor to the resonance hybrid
of the acetate anion, CH3COO−?
a. 1
b. 2
c. 3
d. 4
ANS: C

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BIAF 7e Test Bank 10
54. How many electrons are there in the valence shell of the carbon atom of a methyl cation, CH3+?
a. 4
b. 5
c. 6
d. 7
ANS: C
55. How many electrons are there in the valence shell of the carbon atom of the methyl anion, CH3−?
a. 2
b. 4
c. 6
d. 8
ANS: D
56. How many electrons are there in the valence shell of the oxygen atom of water?
a. 2
b. 4
c. 6
d. 8
ANS: D
57. How many electrons are there in the valence shell of the nitrogen atom of ammonia?
a. 4
b. 5
c. 6
d. 8
ANS: D
58. What is the approximate value of the H−C−H bond angles in a methyl cation, CH3+?
a. 90
b. 109
c. 120
d. 180
ANS: C
59. What is the approximate value of the H−C−H bond angles in a methyl anion, CH3−?
a. 90
b. 109
c. 120
d. 180
ANS: B
60. Which atomic orbitals overlap to form the carbon-hydrogen  bonding molecular orbitals of ethane,
CH3CH3?
a. C2p + H1s
b. C2sp + H1s
c. C2sp2 + H1s
d. C2sp3 + H1s

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BIAF 7e Test Bank 11
ANS: D
61. Which atomic orbitals overlap to form the carbon-hydrogen  bonding molecular orbitals of ethene,
H2C=CH2?
a. C2p + H1s
b. C2sp + H1s
c. C2sp2 + H1s
d. C2sp3 + H1s
ANS: C
62. Which atomic orbitals overlap to form the carbon-carbon  and  bonding molecular orbitals of
ethene, H2C=CH2?
a. C2sp3 + C2sp3, and C2p + C2p
b. C2sp2 + C2sp2, and C2sp2 + C2sp2
c. C2sp2 + C2sp2, and C2p + C2p
d. C2sp3 + C2sp3, and C2sp2 + C2sp2
ANS: C
63. Which atomic orbitals overlap to form the carbon-hydrogen  bonding molecular orbitals of ethyne,
HCCH?
a. C2p + H1s
b. C2sp + H1s
c. C2sp2 + H1s
d. C2sp3 + H1s
ANS: B
64. Which atomic orbitals overlap to form the carbon-carbon  molecular bonding orbital of ethyne,
HCCH?
a. C2p + C2p
b. C2sp + C2sp
c. C2sp2 + C2sp2
d. C2sp3 + C2sp3
ANS: B
65. Which of the following is a primary (1) alcohol?
a. 1
b. 2
c. 3
d. 4
ANS: A

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BIAF 7e Test Bank 13
70. What is the approximate strength of the C−C bond of ethane?
a. 376 kJ/mol (90 kcal./mol)
b. 422 kJ/mol (101 kcal./mol)
c. 556 kJ/mol (133 kcal./mol)
d. 727 kJ/mol (174 kcal./mol)
ANS: A
71. Which of the circled bonds is the strongest?
a. 1
b. 2
c. 3
d. 4
ANS: A
72. Which of the following resonance structures makes the largest contribution to the structure of
[H2CCHO] −?
a. 1
b. 2
c. 3
d. 4
ANS: B

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BIAF 7e Test Bank 14
73. Which of the following shows curved arrows that correctly accounts for the differences between the
two structures?
a. 1
b. 2
c. 3
d. 4
ANS: C
74. Which of the following statements is not true?
a. The sp3C−H bond of an alkane is weaker than the spC−H bond of an alkyne.
b. The carbon-carbon triple bond of an alkyne is shorter than the carbon-carbon bond of
alkenes.
c. The carbon-carbon triple bond of an alkene is exactly three times as strong as a carbon-
carbon single bond of an alkane.
d. The sp3C−H bond of an alkane is longer than the spC−H bond of an alkyne.
ANS: C
75. Which of the following is/are tetrahedral?
1. methane, CH4
2. methyl carbocation, CH3+
3. methyl carbanion, CH3−
4. methyl radical, CH3
a. only 1 and 2
b. only 1 and 3
c. only 1 and 4
d. only 2 and 3
ANS: B

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