Chemistry /Chemistry - Electrochemistry Flashcards

Chemistry - Electrochemistry Flashcards

Chemistry28 CardsCreated about 1 month ago

This deck covers key concepts in electrochemistry, including electrolytes, electrolysis, electrode reactions, and applications of electroplating.

what is an electrolyte

Answer: a substance that conducts electricity when dissolved in water or molten
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Key Terms

Term
Definition

what is an electrolyte

Answer: a substance that conducts electricity when dissolved in water or molten
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Under what two circumstances in which ionic compounds can conduct electricity/ act as electrolytes

Answer: If dissolved in water/ solution, If molten

how can an electric current be conducted through an electrolyte

Answer: ions are available and free to move

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what is electrolysis

Answer: the passing of electricity through an electrolyte to cause a chemical reaction

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what is an electrode

Answer: a solid material that conducts electricity

what occurs at the cathode

Answer: reduction

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TermDefinition

what is an electrolyte

Answer: a substance that conducts electricity when dissolved in water or molten

Under what two circumstances in which ionic compounds can conduct electricity/ act as electrolytes

Answer: If dissolved in water/ solution, If molten

how can an electric current be conducted through an electrolyte

Answer: ions are available and free to move

what is electrolysis

Answer: the passing of electricity through an electrolyte to cause a chemical reaction

what is an electrode

Answer: a solid material that conducts electricity

what occurs at the cathode

Answer: reduction

what occurs at the anode

Answer: oxidation

describe the observations seen (using green copper (II) chromate solutions) Demonstrating the movement of ions when connected to an electrical current

Answer: Observation: a yellow colour will migrate towards the anode and a blue colour will migrate towards the cathode. The yellow colour caused by the chromate ions. The blue colour is caused by the copper (II) ions

Inert electrodes reaction

Answer: electrodes do not react with the electrolyte in which they are placed

Active electrodes reactions

Answer: electrodes that react with the electrolyte in which they are placed

Inert electrodes suitable to use for these electrolysis

Answer: Platinum Graphite (Carbon)

Active electrodes suitable to use for these electrolysis

Answer: Copper electrodes

H2O will always reduce before the following ions

Answer: So4 2-, Na+, K+

what was the result/ Observation Electrolysis of acidified water (H2o + H+) using inert electrodes

Answer: Bubbles of Hydrogen gas will collect over the cathode, Bubbles of oxygen gas will collect over the anode the volume of hydrogen will always be double the amount of oxygen formed (1 mole of hydrogen formed for every half mole oxygen formed)

Balanced chemical equation for reaction at cathode Electrolysis of acidified water (H2o + H+) using inert electrodes

Answer: 2H+ + 2e- → H2↑

balanced chemical equation for reaction at anode Electrolysis of acidified water (H2o + H+) using inert electrodes

Answer: H2O - 2e- → 2H+ + 1/2O2↑

Describe the reaction/ result Electrolysis of sodium sulfate (NaSO4) using inert electrodes

Answer: Bubbles of hydrogen gas will collect over the cathode. The universal indicator turns from green to blue at the cathode. Bubbles of oxygen gas collect over the anode. The universal indicator turns from green to red at the cathode the volume of hydrogen will always be double the amount of oxygen formed (1 mole of hydrogen formed for every half mole oxygen formed)

Balanced chemical equation describing the reaction at the Cathode Electrolysis of sodium sulfate (NaSO4) using inert electrodes

Answer: 2H2O - 2e- → H2↑ + 2OH-

Balanced chemical equation describing the reaction at the anode Electrolysis of sodium sulfate (NaSO4) using inert electrodes

Answer: H2O - 2e- → 2H+ + 1/2O2↑

list the reactions and observations Electrolysis of potassium iodide (KI) solution using inert electrodes

Answer: Bubbles of Hydrogen gas will collect over the cathode Phenolphthalein turns from colourless to pink at the cathode A red-brown colour will form at the anode due to the formation of iodine (I2)

Write a balanced equation for the reaction that occurs at the cathode Electrolysis of potassium iodide (KI) solution using inert electrodes

Answer: 2H2O - 2e- → H2↑ + 2OH-

Write a balanced equation for the reaction that occurs at the anode Electrolysis of potassium iodide (KI) solution using inert electrodes

Answer: 2I- - 2e- → I2

Describe the result/ observation Electrolysis of aqueous copper sulfate (CUSO4) using active electrodes

Answer: The pure copper cathode increases in mass as the Cu 2+ ions in solution are reduced to Cu. The impure copper anode is ‘eaten away’ and decreases in mass and the Cu atoms in the anode are oxidised to CU 2+. Impurities are undissolved and fall to the bottom of the beaker under the anode

describe the reaction at the cathode Electrolysis of aqueous copper sulfate (CUSO4) using active electrodes

Answer: Cu 2+ +2e- → Cu↓

Describe the reaction at the anode | Electrolysis of aqueous copper sulfate (CUSO4) using active electrodes

Answer: Cu - 2e- → CU2+

Give two applications of using electrolysis using active electrodes
Answer: Purification of copper Electroplating
give two examples of electroplating
Answer: cutlery electroplated with silver Bath fittings plated in nickel and chromium
give two advantages to electroplating one metal with another
Answer: the object appears more attractive The object is more resistant to corrosion