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Chemistry - Trends in the Periodic table Flashcards Part 1

Chemistry54 CardsCreated 4 months ago

Groups are the vertical columns in the Periodic Table. Elements within the same group have the same number of electrons in their outermost shell, which gives them similar chemical properties and reactivity.

What are groups

Groups are vertical column. Elements in the same group have the same number of electrons in their outer shell

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Key Terms

Term
Definition

What are groups

Groups are vertical column. Elements in the same group have the same number of electrons in their outer shell

what is a period

A period is a horizontal row. Elements in the have same number of shells

What is the atomic radius

Half the distance between the nuclei of two atoms of the same element that are joined together by a single covalent bond

What is nuclear charge

The force of attraction between the positive protons in the nucleus and the negative electrons in the outer shell.

Why does atomic radius… down the groups of the periodic table

Increases

As you do down a group, each elements has one more shell of electrons than the previous. The negative outer electrons get further a...

What is the screening effect, Down a group

The increase in nuclear charge as you go down a group is lessened by a screening effect. The electrons in the inner shells screen the outer electro...

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TermDefinition

What are groups

Groups are vertical column. Elements in the same group have the same number of electrons in their outer shell

what is a period

A period is a horizontal row. Elements in the have same number of shells

What is the atomic radius

Half the distance between the nuclei of two atoms of the same element that are joined together by a single covalent bond

What is nuclear charge

The force of attraction between the positive protons in the nucleus and the negative electrons in the outer shell.

Why does atomic radius… down the groups of the periodic table

Increases

As you do down a group, each elements has one more shell of electrons than the previous. The negative outer electrons get further away from the positive nucleus. Screening effect increases

What is the screening effect, Down a group

The increase in nuclear charge as you go down a group is lessened by a screening effect. The electrons in the inner shells screen the outer electrons from the positive charge in the nucleus

The atomic radius … across a period because

Decreases, There a increase in effective nuclear charge, No increase in screening effect

What results in increasing nuclear charge

Number of protons increase, number of shells stay the same so the increase in effective nuclear charge,so there is a greater attractive force on the outer electrons

What is First ionisation energy

The minimum energy required to completely remove the most loosely bound electron from a neutral gaseous atom in its ground state

Ionisation energy … down a group because of

Decreases, Increasing screening effect. Increasing atomic radius

Ionisation energy … across a period because of

Increases, Increasing nuclear charge, Decreasing atomic radius

Why do some elements have higher first ionisation energy?

These elements would have full/ half full sublevels. Full or half filled sublevels give an atom extra stability so more energy is required to remove an electron

What is second Ionisation energy of a atom

The energy required to remove an electron from an ion with one positive charge in the gaseous state.

What is the formula for second ionisation energy

X+(g) —-> X2+(g) + e-

( small 2+)

X= element

g= state of matter

What is the first, second and third ionisation energy of potassium

K(g) —-> K+(g) + e-

K+(g) —> K2+ (g) + e-

K2+(g) —> K3+ (g) + e-

Why is there a large increase in ionisation energy whenever electrons are removed from a new sublevel or every level?

Decreased shielding effect

What is electronegativity

The relative attraction that an atom in a molecule has for the shared pair of electrons in a covalent bond

What happens to electronegativity when going down group and why

Electronegativity decreases going down a group.

1.increasing atomic radius

2. Increasing screening effect.

What happens to electronegativity values across a period

Electronegativity increases going across a period. 1 Increasing effective nuclear charge, 2 Decreasing atomic radius

What do the chemical properties of an element depend on?

depends on their type of chemical bonding. How an element forms a bond is due to the number of electrons in the outer shell

Why are Alkali Metals reactive

They have a low ionization energy, the readily lose the single electron in their outer shell

Where are Alkali metals found

They are found in compounds, not free in nature itself

Do the elements of group on lose their outer electrons easier or harder as you go down a group

Easier, because: The atomic radius increases, Screening effect increases

Reactions of Alkali metals with water

They all react vigorously with cold water. Hydrogen gas is given off, metal hydroxide is produced, Speed and violence of the reaction increases as you go down a group- increased reactivity

Describe the reaction of Lithium with water

Lithium floats, fizzes steadily and become smaller until it eventually disappears

Describe the reaction of Sodium with water

The sodium melts to form a ball that moves around on the surface of the water. It fizzes rapidly, the hydrogen produced may produce a orange flame before the sodium disappears

Word equation for reaction of Alkali metals with water

(element) + water ---> (element) hydroxide + hydrogen

Equation for reaction of Alkali metals with water

(element) + H2O ---> (element)OH + 1/2 H2

Reaction of alkali metals with Oxygen

When Alkali metals are cut they initially appear shiny grey but quickly become dull and white as they react with oxygen in the air- this is known as tarnishing

How Lithium reacts with oxygen

Lithium tarnishes slowly due to its relatively slow reaction with oxygen

How Sodium reacts with oxygen

Tarnishes quicker than lithium, its more reactive then Lithium

How Potassium reacts with oxygen

Potassium tarnishes so quickly its difficult to see potassium is actually a shiny metal.

Word equation for reaction of Alkali metals with oxygen

( element) + Oxygen --> (element) oxide

Equation for reaction of Alkali metals with oxygen

2(element) + 1/2 O2 ---> (element)2O

In order for an atom to be stable what rule must it obey?

The octet rule, 8 electrons in the outer shell

When a Halogen element reacts what does it do

It gains one electron

Does the reactivity of halogens increase or decrease as you do down a group, and why?

Decreases, The atomic radius increases, The effective nuclear charge decreases

What can the reactivity of the halogens be shown by?

Displacement reactions

Name and example of displacement reaction for the Halogens

When chlorine( as a gas or dissolved in water), is added to sodium bromide, the chlorine takes the place of the bromine. The chlorine is more reactive than bromine

What’s the word formula for a displacement reaction of chlorine and bromine

Chlorine+ sodium bromide-> sodium chloride +bromide

What do displacement reactions show.

A more reactive halogen displaced a less reactive halogen from a solution of one of its salts.the electronegativity decreases

What is an Oxidising agent

A chemical which causes another chemical to lose an electron and become positivity charged

what is a Redox reaction

One reactant has lost an electron and the other has gained an electron

Redox reactions of the halogens

The halogens are very reactive elements, they are too unstable to exists in a nature in a uncombined form.They often react by taking an electron from another element, they act as oxidising agents. The smaller a halogen atom, the stronger oxidising agent it is.

List the halogens in order of oxidising power

F >Cl >Br >I >At

What is the colour of Chlorine in water

Pale green

What is the colour of Bromine in water

Yellow/ orange

What is the colour of Iodine in water

Brown/red

What is the colour of Chloride ions in water

Colourless

What is the colour of Bromide ions in water

Colourless

What is the colour of Iodide ions in water

Colourless

What is a diatomic molecule

A molecule that is made up of two atoms of the same or different elements

What does AQ stand for in refrence to the state?

aqueous solution

What does the acronym OIL RIG stand for

Oxidation Is Loss, Reduction Is Gain