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OCR A-Level Chemistry: Module 2 - Foundations in Chemistry

Chemistry37 CardsCreated 2 months ago

This flashcard set covers key definitions and concepts related to atomic structure, including isotopes, relative atomic and isotopic mass, and experimental techniques like mass spectrometry. It’s designed for quick recall of foundational chemistry terms and principles.

Define relative isotopic mass (2)

Mass of the isotope compared to 1/12th of the mass of a carbon 12

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Key Terms

Term
Definition

Define relative isotopic mass (2)

Mass of the isotope compared to 1/12th of the mass of a carbon 12

Define isotopes (1)

Atoms with the same number of protons but a different number of neutrons

Explain why isotopes have the same chemical properties (1)

Same number of electrons in the outer shell

Define relative atomic mass (3)

The weighted mean mass of an atom relative to 1/12th the mass of one atom of carbon 12

How could the fraction of the isotopes of carbon be found experimentally? (1)

Mass spectrometry

Explain what is meant by a salt (1)

When the H+ in an acid is replaced by a metal ion

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TermDefinition

Define relative isotopic mass (2)

Mass of the isotope compared to 1/12th of the mass of a carbon 12

Define isotopes (1)

Atoms with the same number of protons but a different number of neutrons

Explain why isotopes have the same chemical properties (1)

Same number of electrons in the outer shell

Define relative atomic mass (3)

The weighted mean mass of an atom relative to 1/12th the mass of one atom of carbon 12

How could the fraction of the isotopes of carbon be found experimentally? (1)

Mass spectrometry

Explain what is meant by a salt (1)

When the H+ in an acid is replaced by a metal ion

What term is given to the .n H2O part of a formula? (1)

Waters of crystallisation

What calcium compound is formed when calcium oxide reacts with water? (1)

Calcium hydroxide

What calcium compound is formed when calcium oxide reacts with nitric acid? (1)

Calcium nitrate

How do old samples of magnesium oxide become contaminated with magnesium carbonate? (1)

MgO has reacted with CO2

A student adds an excess of HCl to magnesium oxide and magnesium carbonate, state two observations that would be made (2)

Solid dissolves

Effervescence

Define an acid (1)

A proton donor

How can CaCO3 be used to combat excess stomach acid? Use an equation (2)


CaCO3 neutralises HCl

CaCO3 + 2HCl -> CaCl2 + H2O + CO2

State an important use of ammonium sulphate (1)

Fertiliser

State a large-scale use of ammonia (1)

Manufacture of explosives

Use oxidation numbers to explain why the reaction involves both oxidation and reduction (algebraically) (3)

X: oxidation number goes up
Y: oxidation number goes down
X is oxidised and Y is reduced

Explain, in terms of electrons, what is meant by oxidation (1)

Loss of electrons

What is meant by the term mole? (1)

Amount of substance that has the same number of particles as there are atoms in 12g of carbon 12

What is a common use of NaClO? (1)

Bleach

Define empirical formula (1)

Simples whole number ratio of atoms

After Ca has fully reacted with HCl, upon adding more Ca, a reaction still takes place, why? (3)

Ca has reacted with water

Ca + 2H2O -> Ca(OH)2 + H2

Explain what is meant by molecular formula (1)

Number and type of atoms making up a molecule

What is meant by ionic bonding? (1)

Electrostatic attraction between oppositely charged ions

Predict the bond angle in an F2O molecule and explain (3)

104.5
There are 2 bonded pairs and 2 lone pairs
Lone pairs repel more than bonded pairs

Describe and explain two anomalous properties of water from hydrogen bonding (4)

Liquid H2O is more dense than solid
Ice has open lattice
H2O has a relatively high boiling point
Hydrogen bonds need to be broken

Magnesium melting point: 650°C
Chlorine melting point: -101°C
Describe the structure and bonding of these elements and explain the difference in melting points (6)

Mg has a giant structure
Mg has metallic bonding
Electrostatic attraction between positive ions and electrons
Cl has a simple covalent lattice
Cl has induced dipole-dipole
Less energy is needed to overcome induced dipole-dipole than metallic bonds

Describe the bonding and structure in graphite

| Explain why graphite is a good conductor, a soft material and a very high melting point (5)

Giant covalent lattice

Arranged in layers

Good conductor - mobile electrons

High melting point - covalent bonds have to be broken

Soft - weak forces between the layers

What is meant by a covalent bond? (1)

A shared pair of electrons

Name the shape of the ammonia molecule and why ammonia has this shape and a bond angle of 107° (3)

Pyramidal
There are 3 bonded pairs and 1 lone pair
Lone pairs repel more than bonded pairs

Why does ammonium chloride not conduct electricity when solid but does when dissolved in water? (2)

Ions cannot move in a solid

| Ions can move in solution

What is meant by metallic bonding? (2)

Electrostatic attraction between the delocalised electrons and the positive ions

Why does H2S have a much lower boiling point than H2O? (2)

No hydrogen bonding

| Weaker intermolecular forces

What is meant by hydrogen bonding? (1)

Interaction between lone pair of F, N or O and a H in a neighbouring molecule

Explain electronegativity (2)

Attraction of an atom for electrons in a covalent bond

Why do O-H and N-H bonds have dipoles? (1)

Oxygen and nitrogen are more electronegative than hydrogen

Why does a water molecule have a different shape to a carbon dioxide molecule? (2)

Electron pairs repel
Oxygen in water has 2 bonds and 2 lone pairs
Carbon in CO2 has 2 double bonds

Why is water a polar molecule, but CO2 is not?

CO2 is symmetrical

| In CO2, dipoles cancel