Essentials of Chemical Reaction Engineering, 2nd Edition Solution Manual

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Solutions Manual forEssentials of ChemicalReaction EngineeringSecond EditionH. Scott FoglerAme and Catherine Vennema Professor of Chemical Engineering andThe Arthur F. Thurnau Professor at the University of Michigan,Ann Arbor, Michigan

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Table of ContentsScreen Shot of Web Home Page .......................................................................................... iScreen Shot of Interactive Computer Games (ICGs).......................................................... iiAlgorithm to Decode ICGs ................................................................................................. vScreen Shot of Polymath Living Example Problems (LEPs)........................................... viiiSample Course Syllabus...................................................................................................... xSolutions to Chapter 1, Problems P1-1 through P1-8Solutions to Chapter 2, Problems P2-1 through P2-10Solutions to Chapter 3, Problems P3-1 through P3-15Solutions to Chapter 4, Problems P4-1 through P4-10Solutions to Chapter 5, Problems P5-1 through P5-26Solutions to Chapter 6, Problems P6-1 through P6-13Solutions to Chapter 7, Problems P7-1 through P7-11Solutions to Chapter 8, Problems P8-1 through P8-18Solutions to Chapter 9, Problems P9-1 through P9-21Solutions to Chapter 10, Problems P10-1 through P10-23Solutions to Chapter 11, Problems P11-1 through P11-10Solutions to Chapter 12, Problems P12-1 through P12-27Solutions to Chapter 13, Problems P13-1 through P13-9

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iWEB HOME PAGE

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iiINTERACTIVE COMPUTER GAMES (ICGs)

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iii

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vALGORITHM TO DECODE ICGs**** CONFIDENTIAL ****UNIVERSITY OF MICHIGANINTERACTIVE COMPUTER MODULES FOR CHEMICAL ENGINEERINGCHEMICAL REACTION ENGINEERING MODULESH. Scott Fogler, Project DirectorM. Nihat Gürmen, Project Manager (2002-2004)Susan Montgomery, Project Manager (1991-1993)Department of Chemical EngineeringUniversity of MichiganAnn Arbor, MI 48109-2136©2005Regents of the University of Michigan- All Rights Reserved -INTERPRETATION OF PERFORMANCE NUMBERSStudents should record their Performance Number for each program, along withthe name of the program, and turn it in to the instructor. The PerformanceNumber for each program is decoded as described in the following pages.The official site for the distribution of the modules ishttp://www.engin.umich.edu/~cre/icmPlease report problems to icm.support@umich.edu.

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viICMs with Windows®interfaceModuleFormatInterpretationExampleKINETIC CHALLENGE ICzBzzAzzScore = 1.5 * AB.CPerf. No. =75241692z = random numbersScore = 1.5*(62.7) = 94%Note: 75% constitutes mastery.KINETIC CHALLENGE IICzBzzAzzScore = 2.0 * AB.CPerf. No. =03776467z = random numbersScore = 2.0*(47.0) = 94%Note: 75% constitutes mastery.MURDER MYSTERYzzAzzA even: Killer and victimPerf. No. = 50732correctly identifiedScore: No creditA odd: Killer and victimnot identifiedz = random numbersNote: An even number for the middle digit constitutesmastery.TIC TAC TOEzDzCzBzAScore = 4.0 * AB.CPerf. No. = 77803581z = random numbersScore = 4*(15.0) = 60configuration 7completedConfigurationsXXXXXXXXXNote: Student receives 20 points for every square answered correctly.A score of 60 is needed for mastery of this module.GREAT RACEzzzCzABzScore = 6.0 * AB.CPerf. No. = 77738078z = random numbersScore = 6*(07.3) = 44Note: A score of 40 is needed for mastery of thismodule.12365487**** CONFIDENTIAL ****

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viiECOLOGYAzBCzaaDz = random numbersa = random charactersA gives info on r^2 value of the student’s linearized plotA=Y if r^2 >= 0.9A=A if 0.9 > r^2 >= 0.8A=X if 0.8 > r^2 >= 0.7A=F if 0.7 > r^2A=Q if Wetland Analysis/Simulator portion has not been completedB gives info on alphaB=1 to 4 => student's alpha < (simulator's alpha0.5)B=5 to 9 => student's alpha > (simulator's alpha0.5)B=X if Wetland Analysis/Simulator portion has not been completedC indicates number of data points deactivated during analysisC=number of deactivated data points if at least 1 point has been deactivatedC=a randomly generated letter from A to Y if 0 points deactivatedC=Z if Wetland Analysis/Simulator portion has not been completedD gives info on solution method used by studentD=1 if polynomial regression was usedD=2 if differential formulas were usedD=3 if graphical differentiation was usedD=4 to 9 if Wetland Analysis/Simulator portion has not been completedPerf No. = A7213DF21)A => 0.9 > r^2 >= 0.82)2 => student’s alpha <(simulator’s alpha0.5)3)1 => one data point wasdeactivated4)2 => differential formulaswere usedSTAGINGzCBzAFzEDz = random numbersPerf. No. = 2125482913Final conversion = 2*AB.Cconversion = 2*42.1 = 84.2Final flow rate = 2*DE.Fflow rate = 2*31.2 = 62.4Please make a pass/fail criterion based on these values.**** CONFIDENTIAL ****

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viiiICMs with Dos®interfaceModuleFormatInterpretationExampleHETCATzzABzCDA=2,3,5,7: interaction donePerf. No. = 8027435B=2,3,5,7: intro doneA: Worked oninteractionC=2,3,5,7: review doneB: Looked at introD denotes how much theyC: Looked at reviewdid in the interaction:D: found parametervalues,didn’t findmechanismD<2Not done2 < D:5 4 Dependences4 < D:5 6 Parameter values6<DMechanismz = random numbersNote: Performance number given only if student goes through theinteraction portion of the moduleHEATFX1zzAzzA even: score > 85 %Perf. No. = 53607z = random numbersScore > 85 %Note: Student told they have achieved mastery if their score isgreater than 85%HEATFX2zzzAzzA even: completed interactionPerf. No. = 407582z = random numbersInteraction notcompletedNote: Performance number given only if student goes through theinteraction portion of the module.**** CONFIDENTIAL ****

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ixLIVING EXAMPLE PROBLEMS (LEPs)

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xSAMPLE COURSE SYLLABUSChE 344: CHEMICAL REACTION ENGINEERINGFundamentals of chemical reaction engineering. Rate laws, kinetics, and mechanisms of homogeneousand heterogeneous reactions. Analysis of rate data, multiple reactions, heat effects, bioreactors. Designof industrial reactors.Prerequisite: ChE 330, ChE 342Fall 2015Lectures: M,W 8:40 (Sharp) to 10:30 (not so sharp) – Room: 1013 DowInstructor:Professor H. Scott Fogler3168 DOW, 763-1361, sfogler@umich.eduOffice Hours: M,W 10:30a to 11:30aCourse assistants include: Instructional aids, tutor, proctors, and gradersText RequiredElements of Chemical Reaction Engineering, 5thedition, H. Scott FoglerWeb site:www.umich.edu/~elements/5eRecommended Reading List•Problem Solving in Chemical and Biochemical Engineering with POLYMATH, Excel,and MATLAB, 2nd Edition 2008, Cutlip & Shacham•The Elements of Style, Strunk and White•Strategies for Creative Problem Solving, 3rd Edition 2014, Fogler, LeBlanc & Rizzo(for OEP’s)Schedule*Note - all ICGs (Interactive Computer Games) are Individual*1) Wednesday, September 9Topic:Lecture 1 – Chapter 1, Introduction, POLYMATH, Mole balancesRead:Preface, Prerequisites, Appendix BIn-Class Problem:No In-Class Problem2) Monday, September 14Topic:Lecture 2 – Chapter 2, Design equations, Levenspiel plots, Reactor stagingRead:Chapter 1, P1-9A, Appendix A, from the WebChapter 2, Sections 2.1, 2.2, and 2.3Hand In:Problem Set 1: P1-1A, P1-6BIn-Class Problem:1Study Problems:P1-8A3) Wednesday, September 16Topic:Lecture 3 – Chapter 3, Rate lawsRead:Chapter 2, Chapter 3Hand In:Problem Set 2: Define terms in the Arrhenius Equation, P2-2A, Intro toLearnchemeIn-Class Problem:2 (Hint:Viewing the University of Alabama YouTube video “The BlackWidow” noted in Problem P3-8Bmay help you with today's in classproblem)

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xiStudy Problems:P2-7A4) Monday, September 21Topic:Lecture 4 – Chapter 4, Stoichiometry Batch SystemsRead:Chapter 4 Section 4.1Hand In:Problem Set 3: Defineθi,θA,θB, andδ, P2-10B, P3-5A, P3-8B, P3-11B, P3-13AIn-Class Problem:3 - Bring i>clickers (tentative) - Test Run of System in 2166 DowStudy Problems:P3-14A5) Wednesday, September 23Topic:Lecture 5 – Chapter 4, Stoichiometry Flow SystemsRead:Chapter 4, Section 4.1Hand In:Problem Set 4: Defineε, FT0, CT0, P4-2A.In-Class Problem:4Study Problems:P4-1Aparts (c) and (d)6) Monday, September 28Topic:Lecture 6 – Chapter 5, Isothermal reactor designRead:Chapter 5, Chapter 5 Summary Notes on the Web siteHand In:Problem Set 5: P4-1A(a) and (b) only, P4-3A, P4-4B, P4-5B.In-Class Problem:5Study Problems:P4-10C7) Wednesday, September 30Topic:Lecture 7 – Chapter 5, California Registration Exam ProblemHand In:Problem Set 6: What are you asked to find P5-18B? What is the ErgunEquation? P5-2A.In-Class Problem:6Study Problems:P5-1B(a) and (b)8) Monday, October 5Topic:Lecture 8 – Chapter 5, Pressure dropRead:Chapter 5, Sections 5.4 and 5.5Hand In:Problem Set 7: P5-3A, P5-4B, P5-5A, P5-8B, P5-13Bomit parts (j) and (k),P5-16B(a).In-Class Problem:7 – Bring LaptopsStudy Problems:P5-9A, P5-10B(a).9) Wednesday, October 7Topic:Lecture 9 – Chapter 6, Membrane ReactorsRead:Chapter 6Hand In:Problem Set 8: P5-13Bpart (j) and (k), P5-22A.In-Class Problem:8 – Bring LaptopsStudy Problems:P5-21B10) Monday, October 12Topic:Lecture 10 – Chapter 6, Semibatch ReactorsRead:Chapter 6Hand In:Problem Set 9: P5-1A(a), P5-11B, P6-4Bdelete part (c), P6-5B.In-Class Problem:9 – Bring Laptops to carry out Polymath ODE SolverStudy Problems:P6-7B

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xii11) Wednesday, October 14Topic:Lecture 11 – Chapter 7, Analysis of Rate Data/Chapter 9, Pseudo Steady StateRead:Chapter 7, Chapter 9, Section 9.1 and the cobra web moduleHand In:Problem Set 10: LEP for Example 6-1, P6-2B, P6-11Bomit part (c)In-Class Problem:10 – Bring Laptops to carry out Polymath RegressionStudy Problems:P7-6B.12) Monday, October 19Topic:No Classes – Fall Study Break13) Wednesday, October 21Topic:Lecture 12 – Chapter 8, Multiple ReactionsRead:Chapter 8, Sections 8.1, 8.2, 8.3 and 8.4;Hand In:Problem Set 11: P7-7A, P7-8A.In-Class Problem:11Study ProblemsP7-10A14) Monday, October 26Topic:Lecture 13 – EXAM I – Covers Chapters 1 through 7 Closedbook, web, notes, in-class problems and home problems.15) Wednesday, October 28Topic:Lecture 14 – Chapter 8: Multiple ReactionsRead:Chapter 8, Sections 8.5, 8.6, 8.7 and 8.8In-Class Problem:12 – Bring LaptopsHand In:Problem Set 12: P8-1A(a) part (1) only, P8-1A(b), P8-1A(c) part (1) only,P8-2B, P8-6B, P8-7C(a), (b) and (c)Study ProblemsP8-10B16) Monday, November 2Topic:Lecture 15 – Derivation of Energy BalanceRead:Chapter 11, Sections 11.1, 11.2 and 11.3Hand In:Problem Set 13: P8-12B. Comprehensive ProblemIn-Class Problem:13 – Bring LaptopsStudy Problems:P8-16A17) Wednesday, November 4Topic:Lecture 16 – Chapter 11: Adiabatic Equilibrium Conversion and ReactorStagingRead:Finish Reading Chapter 11, Equilibrium conversion appendixIn-Class Problem:14Study ProblemsP11-6B18) Monday, November 9Topic:Lecture 17 – Heat Exchange, Adiabatic Reactors ICPsRead:Chapter 12 Sections 12.1 through 12.2Hand In:Problem Set 14: P11-1A(b), P11-3B, P11-4A.In-Class Problem:15Study Problem:P12-6A

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xiii19) Wednesday, November 11Topic:Lecture 18 – Trends in Conversion and Temperature ProfilesApplications of the Energy Balance to PFRsRead:Chapter 12, Section 12.3 and 12.4Hand In:Problem Set 15: P12-3BLEPIn-Class Problem:16 – Bring Laptops20) Monday, November 16Topic:Lecture 19 – Multiple Reactions with Heat EffectsThis topic is a major goal of this course, to carry out calculations for nonisothermal multiple reactions.Applications of the Energy Balance to PFRsHand In:Problem Set 16: P12-4A(a) and (b), P12-14B, P12-17B, P12-21B.In-Class Problem:17 – Bring LaptopsStudy Problem:P12-19B, i>clicker questions handed out in class21) Wednesday, November 18Topic:Lecture 20 – CSTR and Review for Exam II22) Monday, November 23Topic:Lecture 21 – EXAM II – Chapters 8, 11 and 12.Book and notecard are the only materials allowedHand In:Problem Set 17: P12-26C23) Wednesday, November 25Topic:Lecture 22 – Multiple Steady States (MSS)Multiple Reactions with Heat EffectsRead:Sections 12.6 and 12.7In-Class Problem:18 – Bring a Ruler/Straight EdgeStudy Problems:P13-4B24) Monday, November 30Topic:Lecture 23 – Safety (CSI)Read:Chapter 13Hand In:Problem Set 18: P13-1B(b) and (f), P13-8BIn-Class Problem:19 – Bring LaptopsStudy Problems:P13-4B25) Wednesday, December 2Topic:Lecture 24 –Catalysis Reactor SafetyRead:Chapter 13, Sections 13.1 through 13.3, and 13.5Hand In:Problem Set 19: P10-2Apart (d), P10-4BIn-Class Problem:20Study Problems:P12-16B26) Monday, December 7Topic:Lecture 25 – CatalysisRead:Chapter 10, Sections 10.1 through 10.2.2Hand In:Problem Set 20: P10-3A, P10-8B, P10-10BIn-Class Problem:21Study Problems:P10-7B, P10-9B

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